catena-Poly[[aquacopper(II)]-μ2-iminodiacetato-κ4 O,N,O′:O′]
نویسندگان
چکیده
In the title compound, [Cu(C(4)H(5)O(4))(H(2)O)](n), the imino-diacetate (ida) ligands link the Cu(II) atoms into polymeric zigzag chains running along [010]. Each Cu(II) ion is five-coordinated in a distorted square-pyramidal geometry by one N and two O atoms from an ida ligand, one O atom from the neighbouring ida ligand and one water O atom. In the crystal, the polymeric chains are held together via inter-molecular O-H⋯O and N-H⋯O hydrogen bonds.
منابع مشابه
Poly[bis(μ4-acetato-κ4 O:O:O′:O′)bis(μ3-acetato-κ3 O:O:O)(μ2-acetato-κ2 O:O′)(μ2-acetic acid-κ2 O:O′)di-μ-aquacopper(II)trisodium]
In the title compound, [CuNa(3)(CH(3)CO(2))(5)(CH(3)COOH)(H(2)O)(2)](n), the Cu(II) atom lies on an inversion center and is coordinated by four O atoms from four acetate ligands, leading to a square-planar geometry. One Na(I) atom, lying on an inversion center, is coordinated by four O atoms from four acetate ligands and two bridging water mol-ecules in a distorted octa-hedral geometry. The oth...
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